Onium Sulfates and Hydrogen Sulfates: Products of Reactions of Sulfur(IV) Oxide with Aqueous Solutions of Alkylamines and Aniline

Khoma, Ruslan E.Gelmboldt, V. O.Ennan, Alim-Abdul A.Baumer, Vyacheslav N.Rakipov, I. M.Dlubovskiy, R. M.Хома, Руслан Євгенійович2018-10-292018-10-292018Russian Journal of Inorganic Chemistryhttps://dspace.onu.edu.ua/handle/123456789/19299The reaction products formed in the SO2–L–H2O–O2 systems (L is n-propylamine, n-butylamine, tert-butylamine, n-heptylamine, n-octylamine, aniline) were isolated and identified as “onium” salts [n-C3H7NH3]2SO4, [n-C4H9NH3]2SO4, [t-C4H9NH3]2SO4, [n-C7H15NH3]3SO4(HSO4), [n-C8H17NH3]3SO4(HSO4), and [C6H5NH3]2SO4. The products were characterized by elemental analysis, IR and Raman spectroscopy, mass spectrometry, and thermogravimetryenonium sulfateshydrogen sulfatessulfur(IV) oxideOnium Sulfates and Hydrogen Sulfates: Products of Reactions of Sulfur(IV) Oxide with Aqueous Solutions of Alkylamines and AnilineArticlehttps://doi.org/10.1134/S0036023618050157