Synthesis and structural characteristics of bis(citrate)germanates(IV) (Hbipy)2[Ge(HCit)2]∙2H2O and [CuCl(bipy)2]2[Ge(HCit)2]∙8H2O

Seifullina, Inna Y.Martsynko, Olena E.Chebanenko, Olena AnatoliivnaPirozhok, OlhaDyakonenko, Viktoriya VolodymyrivnaShishkina, SvitlanaМарцинко, Елена ЭдуардовнаМарцинко, Олена ЕдуардівнаСейфулліна, Інна ЙосипівнаСейфуллина, Инна Иосифовна2018-02-022018-02-022016Chemistry Journal of Moldova. General, Industrial and Ecological Chemistryhttps://dspace.onu.edu.ua/handle/123456789/12677The crystalline compounds (Hbipy)2[Ge(HCit)2]·2H2O (1) and [CuCl(bipy)2]2[Ge(HCit)2]·8H2O (2) (where H4Cit is citric acid, bipy is 2,2ʹ-bipyridine) were obtained for the fi rst time and their structures were determined by the single-crystal X-ray diffraction method. Compounds were characterized by IR spectroscopy, thermogravimetric (TGA) and elemental analyses. Both compounds are formed with complex bis(citrate)germanate anion and protonated 2,2’-bipyridine or [Cu(bipy)2Cl]+ as cations in compounds 1 and 2, respectively.engermanium(IV) compoundcitric acid2,2’-bipyridinecopper(II) complexstructureSynthesis and structural characteristics of bis(citrate)germanates(IV) (Hbipy)2[Ge(HCit)2]∙2H2O and [CuCl(bipy)2]2[Ge(HCit)2]∙8H2OArticle