Перегляд за Автор "Pirozhok, Olha"

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    Synthesis and structural characteristics of bis(citrate)germanates(IV) (Hbipy)2[Ge(HCit)2]∙2H2O and [CuCl(bipy)2]2[Ge(HCit)2]∙8H2O
    (2016) Seifullina, Inna Y.; Martsynko, Olena E.; Chebanenko, Olena Anatoliivna; Pirozhok, Olha; Dyakonenko, Viktoriya Volodymyrivna; Shishkina, Svitlana; Марцинко, Елена Эдуардовна; Марцинко, Олена Едуардівна; Сейфулліна, Інна Йосипівна; Сейфуллина, Инна Иосифовна
    The crystalline compounds (Hbipy)2[Ge(HCit)2]·2H2O (1) and [CuCl(bipy)2]2[Ge(HCit)2]·8H2O (2) (where H4Cit is citric acid, bipy is 2,2ʹ-bipyridine) were obtained for the fi rst time and their structures were determined by the single-crystal X-ray diffraction method. Compounds were characterized by IR spectroscopy, thermogravimetric (TGA) and elemental analyses. Both compounds are formed with complex bis(citrate)germanate anion and protonated 2,2’-bipyridine or [Cu(bipy)2Cl]+ as cations in compounds 1 and 2, respectively.