Please use this identifier to cite or link to this item:
Title: Schiff bases complexes immobilized at nanosilica as catalysts in ozone decomposition
Authors: Rakitskaya, Tatiana L.
Truba, Hanna M.
Radchenko, E. O.
Golub, A. А.
Ракитська, Тетяна Леонідівна
Ракитская, Татьяна Леонидовна
Труба, Ганна Миколаївна
Труба, Анна Николаевна
Citation: Nanoscale Research Letters
Issue Date: 2015
Keywords: nanocatalysts
ozone decomposition
Series/Report no.: ;Vol. 10.
Abstract: The influence of Mn(II), Co(II), Cu(II), Zn(II) and ligands, L1 and L2 (Fig) on nanocatalysts catalytic activity in ozone decomposition reaction were studied. The immobilization of a ligand and a complex formation were proved by IR and UV-VIS spectroscopy. When the complex is formed it shifts C=N band in IR spectra to shorter wavelengths. The shift of band in UV-VIS spectra is also an evidence for a metal coordination. The half time of ozone decomposition (the bigger the better) is an evaluation parameter of complex activity. The influence of a central atom on catalytic activity of a mono complex could be represented as follows:
Appears in Collections:Статті та доповіді ФХФ

Files in This Item:
File Description SizeFormat 
101.pdf416.03 kBAdobe PDFThumbnail

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.