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|Title:||Schiff bases complexes immobilized at nanosilica as catalysts in ozone decomposition|
|Authors:||Rakitskaya, Tatiana L.|
Truba, Hanna M.
Radchenko, E. O.
Golub, A. А.
Ракитська, Тетяна Леонідівна
Ракитская, Татьяна Леонидовна
Труба, Ганна Миколаївна
Труба, Анна Николаевна
|Citation:||Nanoscale Research Letters|
|Series/Report no.:||;Vol. 10.|
|Abstract:||The influence of Mn(II), Co(II), Cu(II), Zn(II) and ligands, L1 and L2 (Fig) on nanocatalysts catalytic activity in ozone decomposition reaction were studied. The immobilization of a ligand and a complex formation were proved by IR and UV-VIS spectroscopy. When the complex is formed it shifts C=N band in IR spectra to shorter wavelengths. The shift of band in UV-VIS spectra is also an evidence for a metal coordination. The half time of ozone decomposition (the bigger the better) is an evaluation parameter of complex activity. The influence of a central atom on catalytic activity of a mono complex could be represented as follows:|
|Appears in Collections:||Статті та доповіді ФХФ|
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