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Title: The products of SO2 interaction with aqueous solutions of methylamine, benzylamines, 1,2-diamines and morpholine
Authors: Khoma, Ruslan Ye.
Gelmboldt, V. O.
Ennan, Alim-Abdul A.
Baumer, Vyacheslav N.
Mazepa, A. V.
Koksharova, Tatiana V.
Кокшарова, Тетяна Володимирівна
Хома, Руслан Євгенійович
Citation: XVIII-th International Conference “Physical Methods in Coordination and Supramolecular Chemistry”. October 8-9, 2015, Chişinău, Moldova.
Issue Date: 2015
Keywords: Onium sulfates
method of preparation
Abstract: The new method of preparation of sulphuroxoanions “onium ” salts via interaction in the SO 2- L -H2O -O2 systems (L. is methylamine, bonzylamines, 12 -diamines, and morpholine) has been developed. Onium sulfates have been obtained from methylamine, benzylamine, a-phcnylethylamine, N,N -dimethylbenzylamine, dibenzylamine, 1 ,2-ethylenenediamine, morpholine, N,N,N\N3- tetramethylethylenediamine; sulphitesmonohyd rates - from piperazine and N -(hydroxyethyl)ethylenediamine; dithionate - from piperazine and N,N,N\N 3-tetramethylethylenediamine. The compounds were characterized by elemental analysis, X-ray diffraction, IR, Raman spectroscopy, mass spectrometry, and differential thermal analysis.
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