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Title: | Synthesis and structural characteristics of bis(citrate)germanates(IV) (Hbipy)2[Ge(HCit)2]∙2H2O and [CuCl(bipy)2]2[Ge(HCit)2]∙8H2O |
Authors: | Seifullina, Inna Y. Martsynko, Olena E. Chebanenko, Olena Anatoliivna Pirozhok, Olha Dyakonenko, Viktoriya Volodymyrivna Shishkina, Svitlana Марцинко, Елена Эдуардовна Марцинко, Олена Едуардівна Сейфулліна, Інна Йосипівна Сейфуллина, Инна Иосифовна |
Citation: | Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry |
Issue Date: | 2016 |
Keywords: | germanium(IV) compound citric acid 2,2’-bipyridine copper(II) complex structure |
Series/Report no.: | ;Vol. 11(2). |
Abstract: | The crystalline compounds (Hbipy)2[Ge(HCit)2]·2H2O (1) and [CuCl(bipy)2]2[Ge(HCit)2]·8H2O (2) (where H4Cit is citric acid, bipy is 2,2ʹ-bipyridine) were obtained for the fi rst time and their structures were determined by the single-crystal X-ray diffraction method. Compounds were characterized by IR spectroscopy, thermogravimetric (TGA) and elemental analyses. Both compounds are formed with complex bis(citrate)germanate anion and protonated 2,2’-bipyridine or [Cu(bipy)2Cl]+ as cations in compounds 1 and 2, respectively. |
URI: | http://dspace.onu.edu.ua:8080/handle/123456789/12677 |
Appears in Collections: | Статті та доповіді ФХФ |
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