Please use this identifier to cite or link to this item: http://dspace.onu.edu.ua:8080/handle/123456789/12677
Title: Synthesis and structural characteristics of bis(citrate)germanates(IV) (Hbipy)2[Ge(HCit)2]∙2H2O and [CuCl(bipy)2]2[Ge(HCit)2]∙8H2O
Authors: Seifullina, Inna Y.
Martsynko, Olena E.
Chebanenko, Olena Anatoliivna
Pirozhok, Olha
Dyakonenko, Viktoriya Volodymyrivna
Shishkina, Svitlana
Марцинко, Елена Эдуардовна
Марцинко, Олена Едуардівна
Сейфулліна, Інна Йосипівна
Сейфуллина, Инна Иосифовна
Citation: Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry
Issue Date: 2016
Keywords: germanium(IV) compound
citric acid
2,2’-bipyridine
copper(II) complex
structure
Series/Report no.: ;Vol. 11(2).
Abstract: The crystalline compounds (Hbipy)2[Ge(HCit)2]·2H2O (1) and [CuCl(bipy)2]2[Ge(HCit)2]·8H2O (2) (where H4Cit is citric acid, bipy is 2,2ʹ-bipyridine) were obtained for the fi rst time and their structures were determined by the single-crystal X-ray diffraction method. Compounds were characterized by IR spectroscopy, thermogravimetric (TGA) and elemental analyses. Both compounds are formed with complex bis(citrate)germanate anion and protonated 2,2’-bipyridine or [Cu(bipy)2Cl]+ as cations in compounds 1 and 2, respectively.
URI: http://dspace.onu.edu.ua:8080/handle/123456789/12677
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