Synthesis, structure and investigation of germanium(iv) and copper(ii) complexes with malic acid and 1,10’-phenanthroline
Вантажиться...
Дата
2017
Науковий керівник
Укладач
Редактор
Назва журналу
Номер ISSN
Номер E-ISSN
Назва тому
Видавець
Анотація
Two crystalline compounds of germanium(IV) with malic acid (H3Mal) and 1,10’-phenanthroline (phen) - [Ge(HMal)2(phen)]·phen·2H2O (1) and [CuCl(phen)2][Ge(OH)(HMal)2] (2) were synthesized for the first time and characterized by elemental analysis, IR spectroscopy and thermogravimetric analysis. Using single crystal X-ray diffraction, two different forms of germanium were elucidated: Ge4+ (1) and hydrolyzed GeOH3+ (2) with a distorted octahedron and pyramid surrounding geometry, respectively.
Опис
Ключові слова
germanium(IV) compound, malic acid, 1,10’-phenanthroline, copper(II) complex, structure
Бібліографічний опис
Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry