Please use this identifier to cite or link to this item: http://dspace.onu.edu.ua:8080/handle/123456789/12648
Title: Synthesis, structure and investigation of germanium(iv) and copper(ii) complexes with malic acid and 1,10’-phenanthroline
Authors: Seifullina, Inna Y.
Martsynko, Olena E.
Chebanenko, Olena Anatoliivna
Afanasenko, E. V.
Dyakonenko, Viktoriya Volodymyrivna
Shishkina, Svitlana
Марцинко, Елена Эдуардовна
Марцинко, Олена Едуардівна
Сейфулліна, Інна Йосипівна
Сейфуллина, Инна Иосифовна
Citation: Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry
Issue Date: 2017
Keywords: germanium(IV) compound
malic acid
1,10’-phenanthroline
copper(II) complex
structure
Series/Report no.: ;Vol. 12(2).
Abstract: Two crystalline compounds of germanium(IV) with malic acid (H3Mal) and 1,10’-phenanthroline (phen) - [Ge(HMal)2(phen)]·phen·2H2O (1) and [CuCl(phen)2][Ge(OH)(HMal)2] (2) were synthesized for the first time and characterized by elemental analysis, IR spectroscopy and thermogravimetric analysis. Using single crystal X-ray diffraction, two different forms of germanium were elucidated: Ge4+ (1) and hydrolyzed GeOH3+ (2) with a distorted octahedron and pyramid surrounding geometry, respectively.
URI: http://dspace.onu.edu.ua:8080/handle/123456789/12648
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